Publication | Closed Access
Synthesis and Application of Polymer‐Supported Chiral Brønsted Acid Organocatalysts
131
Citations
96
References
2010
Year
Tea‐bag ApproachChemical EngineeringEnantioselective SynthesisEngineeringNovel OrganocatalystsNatural SciencesDiversity-oriented SynthesisOrganic ChemistryChiral Brønsted AcidsNew MethodologyCatalysisHomogeneous CatalysisChemistryAsymmetric CatalysisPolymer ChemistryCatalytic SynthesisPolymers
Abstract A new methodology for the immobilization of chiral Brønsted acids has been developed. The resulting heterogeneous organocatalysts have been employed in multiple consecutive catalysis cycles in the asymmetric organocatalytic transfer hydrogenation. The new catalyst system can not only be easily recovered from the reaction mixture in a tea‐bag approach but it can also be easily reused in several catalytic cycles without loss of reactivity and selectivity.
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