Concepedia

High conversion of olefins to cis-diols by non-heme iron catalysts and H2O2

Ju Yeon Ryu, Jinheung Kim, Miguel Costas, Kui Chen, Wonwoo Nam, Lawrence Que

Chemical Communications · 2002 · 84 citations · 16 references

DOI

Concepts

Abstract

Efficient and highly stereoselective oxidation of olefins to cis-diols as the major product is obtained by using biomimetic non-heme FeII catalysts in combination with H2O2.

References

16

Stereospecific Alkane Hydroxylation by Non-Heme Iron Catalysts:  Mechanistic Evidence for an Fe<sup>V</sup>O Active Species

Kui Chen, Lawrence Que · Journal of the American Chemical Society · 2001 · 479 citations

, , +17

Olefin Cis-Dihydroxylation versus Epoxidation by Non-Heme Iron Catalysts:  Two Faces of an Fe<sup>III</sup>−OOH Coin

Kui Chen, Miguel Costas, Jinheung Kim et al. · Journal of the American Chemical Society · 2002 · 462 citations

, , +15

Models for Nonheme Iron Intermediates:  Structural Basis for Tuning the Spin States of Fe(TPA) Complexes

Yan Zang, Jinheung Kim, Yanhong Dong et al. · Journal of the American Chemical Society · 1997 · 326 citations

, , +17

Stereospecific Alkane Hydroxylation with H<sub>2</sub>O<sub>2</sub>Catalyzed by an Iron(II)−Tris(2-pyridylmethyl)amine Complex

Cheal Kim, Kui Chen, Jinheung Kim et al. · Journal of the American Chemical Society · 1997 · 310 citations

, , +15

Osmium-Catalyzed Dihydroxylation of Olefins Using Dioxygen or Air as the Terminal Oxidant

Christian Döbler, Gerald Mehltretter, Uta Sundermeier et al. · Journal of the American Chemical Society · 2000 · 181 citations

, , +12