Preparation, Characterization, and Photocatalytic Applications of MWCNTs/TiO<sub>2</sub>Composite

Ahmed M. Kamil, Falah H. Hussein, Ahmed F. Halbus, Detlef W. Bahnemann

International Journal of Photoenergy · 2014 · 44 citations · 30 references

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Abstract

The multiwall carbon nanotubes (MWCNTs)/titanium dioxide (P25) composite in different ratios was prepared using simple evaporation and drying process. The composite was characterized by Raman spectroscopy, X - ray diffraction (XRD), UV - visible diffuse reflectance spectroscopy, and scanning electron microscopy (SEM). The photocatalytic activity of this composite was investigated using degradation of the Bismarck brown R dye (BBR). An optimal MWCNTs/TiO 2 ratio of 0.5% (w/w) was found to achieve the maximum rate of BBR degradation. It was observed that the composite exhibits enhanced photocatalytic activity compared with TiO 2 . The enhancement in photocatalytic activity performance of the MWCNTs/P25 composite is explained in terms of recombination of photogenerated electron-hole pairs. In addition, MWCNTs act as a dispersing support to control the morphology of TiO 2 particles in the MWCNTs/TiO 2 composite.

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