Angewandte Chemie International Edition · 2005 · 728 citations · 33 references
Natural SciencesChemical EngineeringChemistryOrganic ChemistrySeparation ScienceSurface ScienceAdsorption ProcessesAdsorptive SeparationsSolvent ExtractionSurface AdsorptionSurface PhysicsAdsorbent Materials For Gas SeparationAdsorption SeparationAdsorption-based SeparationMetal-organic Framework AdsorptionMetal-organic FrameworksMicroporous Adsorbents
Separating the wheat from the chaff: The microporous metal–organic framework (MMOF) of [Cu(hfipbb)(H2hfipbb)0.5] is based on a bimetallic paddle-wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 44 nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C2, C3, and n-C4 olefins and alkanes (see picture).
33
Hydrogen Storage in Microporous Metal-Organic Frameworks
Nathaniel L. Rosi, Juergen Eckert, Mohamed Eddaoudi et al. · Science · 2003 · 4.8K citations
Highly controlled acetylene accommodation in a metal–organic microporous material
Ryotaro Matsuda, Ryo Kitaura, Susumu Kitagawa et al. · Nature · 2005 · 1.5K citations
Natural Sciences, Materials Engineering, Materials Science +10