Concepedia

Gold‐Catalyzed Allyl–Allyl Coupling

Susana Porcel, Verónica López‐Carrillo, Cristina García‐Yebra, Antonio M. Echavarren

Angewandte Chemie International Edition · 2008 · 76 citations · 38 references

DOI

Concepts

Abstract

Gold rings: Cationic gold(I) complexes efficiently catalyze the intramolecular allyl–allyl coupling of allyl acetates with allylstannanes with excellent stereoselectivity (see scheme). This reaction is mechanistically very different from that catalyzed by palladium.

References

38

Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids

Alois Fürstner, Paul Davies · Angewandte Chemie International Edition · 2007 · 2.3K citations

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Intramolecular [4 + 2] Cycloadditions of 1,3-Enynes or Arylalkynes with Alkenes with Highly Reactive Cationic Phosphine Au(I) Complexes

Cristina Nieto‐Oberhuber, Salomé López, Antonio M. Echavarren · Journal of the American Chemical Society · 2005 · 561 citations

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Hydroamination and Hydroalkoxylation Catalyzed by Triflic Acid. Parallels to Reactions Initiated with Metal Triflates

Devon C. Rosenfeld, Shashank Shekhar, Akihiro Takemiya et al. · Organic Letters · 2006 · 362 citations

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Catalysis by Gold(I) and Gold(III): A Parallelism between Homo‐ and Heterogeneous Catalysts for Copper‐Free Sonogashira Cross‐Coupling Reactions

Camino González‐Arellano, Alberto Abad, Avelino Corma et al. · Angewandte Chemie International Edition · 2007 · 304 citations

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Gold(III)-Catalyzed Nucleophilic Substitution of Propargylic Alcohols

Marie Georgy, Valérie Boucard, Jean‐Marc Campagne · Journal of the American Chemical Society · 2005 · 300 citations · Full text

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