Chemical Communications · 2003 · 46 citations · 17 references
Materials ScienceMolecular SieveChemical EngineeringCross-coupling ReactionEngineeringPd-silica CatalystsSilica PrecursorsSurface ScienceHeterogeneous CatalysisCatalysisChemistryHeck CouplingCatalyst PreparationCatalyst ActivationCatalytic Synthesis
Pd-silica catalysts prepared by depositing Pd onto silica precursors modified by surface methyl or phenyl groups through the reduction of Pd2+ ions with surface Si-H functions exhibit high activity and selectivity in Heck coupling.
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Klaus Köhler, Roland G. Heidenreich, Jürgen G.E. Krauter et al. · Chemistry - A European Journal · 2002 · 384 citations