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Oxidation-resistant, sterically demanding phenanthrolines as supporting ligands for copper(<scp>i</scp>) nitrene transfer catalysts
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Citations
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References
2004
Year
Materials ScienceInorganic ChemistryChemical EngineeringNitrene Transfer CatalystsElectron-rich ArenesEngineeringCoordination ComplexHeterogeneous CatalysisOrganic ChemistryCationic CopperOrganometallic CatalysisCatalysisMolecular ComplexChemistryInorganic SynthesisNew 1,10-Phenanthroline Ligands
New 1,10-phenanthroline ligands have been synthesized with C6F5- or 2,4,6-(CF3)3C6H2- groups in the 2- and 9-positions; a cationic copper(I) complex of the latter catalyses nitrene transfer to the C-H bonds of electron-rich arenes.
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