Hydrogen bonding and CH/π interactions for the stabilization of biomimetic zinc complexes: first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center - Concepedia

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Hydrogen bonding and CH/π interactions for the stabilization of biomimetic zinc complexes: first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center

54

Citations

8

References

2001

Year

Olivier Sénèque, Olivia Reinaud, Michel Giorgi

Chemical Communications

Inorganic ChemistryChemical EngineeringGuest Ligand LEngineeringBiochemistryNatural SciencesCoordination ComplexX-ray Characterized AlcoholMolecular ComplexHydrogen BondingChemistryAmide AdductsCh/π InteractionsInorganic Compound

Abstract

X-Ray analysis of two biomimetic (N3ZnL)2+ complexes with L = ethanol and formamide revealed that hydrogen bonding and CH/π interactions between the guest ligand L and the calix[6]arene host structure play a key role in their stabilization.

References

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