Reactivity and Operational Stability of <i>N</i>‐Tailed TAMLs through Kinetic Studies of the Catalyzed Oxidation of Orange II by H₂O₂: Synthesis and X‐ray Structure of an <i>N</i>‐Phenyl TAML

Abstract

Invited for the cover of this issue are Terrence J. Collins and co-workers at Carnegie Mellon University (USA) and the National Chemical Laboratory (India). The image depicts five generations of tetraamido macrocyclic ligand (TAML) activators, which are small molecule, full-functional mimics of oxidizing enzymes that arguably outperform the peroxidase enzymes they mimic. Read the full text of the article at 10.1002/chem.201406061.