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The first synthesis of chiral phosphinocarboxylic acid ligands, trans-2-(diphenylphosphino)cycloalkanecarboxylic acids. The phosphine-palladium complexes catalyzed asymmetric allylic alkylation

Asymmetric CatalysisFirst SynthesisCross-coupling ReactionEngineeringAsymmetric Allylic AlkylationOrganic ChemistryOrganometallic CatalysisCatalysisChemistryPhosphine-palladium ComplexesSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering