Concepedia

Asymmetric aziridination of chalcones catalyzed by a novel backbone 1,8-bisoxazolinylanthracene (AnBOX)-copper complexElectronic supplementary information (ESI) available: characterization data, 1H NMR and 13C NMR spectra for the ligand AnBOX 1 and all unknown compounds 3, and HPLC chromatograms for the determination of the ee values of all the aziridine derivatives 3. See http://www.rsc.org/suppdata/cc/b4/b404134h/

Jiaxi Xu, Linge Ma, Peng Jiao

Chemical Communications · 2004 · 65 citations · 19 references

DOI

Concepts

Abstract

Highly enantioselective aziridination of chalcones catalyzed by a novel backbone 1,8-bisoxazolidinylanthracene (AnBOX) and CuOTf with up to >99% ee and the opposite enantioselectivity compared with the ligands of Evans are described.

References

19

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, , +7