Concepedia

Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character

Xiaoming He, Ruth A. Bartlett, Marilyn M. Olmstead, K. Ruhlandt‐Senge, Bradley E. Sturgeon, Philip P. Power

Angewandte Chemie International Edition in English · 1993 · 145 citations · 8 references

DOI

Concepts

Abstract

The shortening of the GaGa bond in Trip2GaGaTrip2 (1, TripH  2,4,6-iPr3C6H3) by 0.17 Å to 2.343(2) Å on formation of the radical anion 1˙− is due, at least in part, to the formation of a one-electron π bond between the gallium atoms.

References

8

Tetrakis[bis(trimethylsilyl)methyl]dialan(4), eine Verbindung mit Aluminium—Aluminium-Bindung

Werner Uhl · Zeitschrift für Naturforschung B · 1988 · 303 citations · Full text

, , +8

Boron-boron double bonding in the species [B2R4]2-: synthesis and structure of [{(Et2O)Li}2{Mes2BB(Mes)Ph}], a diborane(4) dianion analog of a substituted ethylene

Afarin Moezzi, Marilyn M. Olmstead, Philip P. Power · Journal of the American Chemical Society · 1992 · 191 citations

, , +5

An AlAl One‐Electron π Bond

Christian Pluta, Klaus‐R. Pörschke, Carl Krüger et al. · Angewandte Chemie International Edition in English · 1993 · 124 citations

, , +10

Reduction of a Boron–Nitrogen 1,3‐Butadiene Analogue: Evidence for a Strong BB π‐Bond

Afarin Moezzi, Ruth A. Bartlett, Philip P. Power · Angewandte Chemie International Edition in English · 1992 · 122 citations

, , +6

A Boron‐Boron One‐Electron π‐Bond

Hartmut Klusik, Armin Berndt · Angewandte Chemie International Edition in English · 1981 · 116 citations

, , +10