Chemistry Letters · 2010 · 412 citations · 17 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistrySolid-state ChemistryCrystal ChemistryCrystal LatticeCrystal SymmetryCrystallographyStructure DeterminationX-ray CrystallographyCrystal Structure AnalysisCrystal Structure DeterminationIon MigrationIon Migration PathwaysLithium Intercalation CompoundsLithium-ion ConductivityLithium-ion ConductorsSingle Crystal Analysis
Abstract The detailed crystal structure of cubic Li7La3Zr2O12 has been successfully determined by single-crystal X-ray structure analysis. The three-dimensional network of the Li-ion migration pathway with short Li–Li distance and occupational disordering is formed in the garnet-type framework structure. The basic unit of the pathway can be expressed as a loop constructed by the Li1 and Li2 sites. The loop links to another one, where only the Li1 site is shared by two loops as a junction.
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High ionic conductivity in lithium lanthanum titanate
Yoshiyuki Inaguma, Mitsuru Itoh, Takashi Uchida et al. · Solid State Communications · 1993 · 1.6K citations