Angewandte Chemie International Edition · 2012 · 334 citations · 16 references
Natural SciencesChemistryCatalysisGreen ChemistryInorganic ChemistryCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MaterialsCatalytic MechanismsZeolite CatalysisBaeyer-villiger OxidationLewis Acid CatalysisLewis AcidityTransition Metal-catalyzed SynthesisZeolite Catalyst DesignZeolite Catalyst SynthesisZeolite CatalystsZeolites
Tin goes in: The solid Lewis acid Sn-zeolite β is obtained in a simple and scalable procedure (see scheme). A high metal content can be obtained, without undesirable side-effects. The space-time-yields of the resulting catalysis are over one order-of-magnitude larger than those of the state-of-the-art materials for the Baeyer–Villiger oxidation of cyclohexanone and the synthesis of ethyl lactate from the triose dihydroxyacetone.
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