Study of decomposition products by gas chromatography-mass spectrometry and ion chromatography-electrospray ionization-mass spectrometry in thermally decomposed lithium hexafluorophosphate-based lithium ion battery electrolytes

Abstract

In this work, the thermal decomposition of a lithium ion battery electrolyte (1 M LiPF₆ in ethylene carbonate/ethyl methyl carbonate, 50/50 wt%) with a focus on the formation of organophosphates was systematically studied.