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Novel, Acentric Metal–Organic Coordination Polymers from Hydrothermal Reactions Involving In Situ Ligand Synthesis
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2002
Year
EngineeringOrganic ChemistryChemistryHydrothermal Reactions InvolvingPolymersInorganic CompoundChemical EngineeringOrganometallic CatalysisMetal-organic PolyhedronPolymer ChemistryMaterials ScienceInorganic ChemistryCoordination PolymersCatalysisInorganic SynthesisBiomolecular EngineeringSitu Ligand SynthesisCoordination ComplexPyridyltetrazolate LigandSecond Harmonic GenerationMolecular ComplexCoordination Polymer
The pyridyltetrazolate ligand formed in situ from NaN3 and 3-cyanopyridine in the presence of ZnCl2 or CdCl2 in water affords acentric (1) or chiral (2) coordination polymers, respectively. The corresponding reaction of ZnCl2 with 4-cyanopyridine gives acentric 3 (not shown). Compounds 1–3 are second harmonic generation active.