A Switchable NLO Organic‐Inorganic Compound Based on Conformationally Chiral Disulfide Molecules and Bi(III)I₅ Iodobismuthate Networks

Abstract

A novel organic-inorganic hybrid based on cystamine and BiI5 chains is prepared. Due to the flexibility of the disulfide molecules in the structure, single crystals or crystalline thin films of this hybrid undergo a reversible acentric-to-centric structural transition at moderate conditions (T = 36.8 °C). This makes the title compound an excellent candidate for temperature controlled SHG or THG switches. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2089/2008/c1753_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.