Concepedia

Mn(<scp>iii</scp>)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines

Jia‐Jia Cao, Xiang Wang, Shun‐Yi Wang, Shun‐Jun Ji

Chemical Communications · 2014 · 65 citations · 31 references

DOI

Concepts

Abstract

Mn(III)-mediated reactions of 2-isocyanobiaryls with 1,3-dicarbonyl compounds were described for the construction of 6-alkylated and 6-monofluoro-alkylated phenanthridines in moderate to good yields. The reaction involves formation of two new C-C bonds and one C-C bond cleavage.

References

31

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