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ε<sup>6</sup>-Phosphinine-and ε<sup>6</sup>-1,3-Diphosphinine Iron Complexes
12
Citations
2
References
1996
Year
Inorganic ChemistryEngineeringBiochemistryNatural SciencesCoordination ComplexDiversity-oriented SynthesisPyridine FormationMolecular BiologyUnsaturated Free FourOrganometallic CatalysisSynthetic ChemistryMolecular ComplexChemistryOrganophosphorus RingsInorganic SynthesisBiomolecular Engineering
Abstract Efficient synthetic routes are described, leading to novel η6-phosphinine- (1) and η6-1,3-diphosphinine (4, 5) iron(0) complexes. 1 is a catalyst for pyridine formation by a [2+2+2]-cyclic addition reaction of nitriles and alkynes and s4 is a useful source of unsaturated free four and six membered organophosphorus rings.
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