Fast Ion‐Transfer Processes at Nanoscopic Liquid/Liquid Interfaces

Abstract

Keeping up: The fastest kinetic data for ion transfer at a liquid/liquid interface were evaluated by nanopipette voltammetry. The steady-state voltammograms can be explained by theoretical models. In previous electrochemical measurements the systematic underestimation of k0 is probably a result of inefficient mass transfer to the relatively large interface. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.