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A new selective approach to unsymmetrical siloxanes and germasiloxanes via O-metalation of silanols with 2-methylallylsilanes and 2-methylallylgermanes
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Citations
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References
2011
Year
Materials ScienceInorganic ChemistryChemical EngineeringUnsymmetrical SiloxanesEngineeringAlkene MetathesisCross-coupling ReactionMild ConditionsNew Selective ApproachOrganic ChemistryTrifluoromethanesulfonate-catalyzed O-metalationCatalysisOrganometallic CatalysisChemistryBond FormationAsymmetric CatalysisSynthetic ChemistryEnantioselective Synthesis
A scandium(III) trifluoromethanesulfonate-catalyzed O-metalation of silanols with 2-methylallylsilanes and 2-methylallylgermanes leading to siloxane or germasiloxane bond formation under mild conditions with evolution of isobutylene is described.
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