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[Mo<sub>57</sub>Fe<sub>6</sub>(NO)<sub>6</sub>O<sub>174</sub>(OH)<sub>3</sub>(H<sub>2</sub>0)<sub>24</sub>]<sup>15−</sup>: A Highly Symmetrical Giant Cluster with an Unusual Cavity and the Possibility of Positioning Paramagnetic Centers on Extremely Large Cluster Surfaces
80
Citations
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References
1994
Year
Crystal StructureEngineeringMagnetic ResonanceOrganic ChemistryChemistryCentral O33 PolyhedronLarge Cluster SurfacesUnusual CavityMaterials ScienceInorganic ChemistryPositioning Paramagnetic CentersCluster SciencePhysicsPhysical ChemistryCrystallographyCrystal Structure DesignNatural SciencesCondensed Matter PhysicsCluster ChemistryMain Group ChemistryGiant Cluster
Three hundred and twenty-seven atoms with a combined molecular weight of 9250.9 Da make up the title compound, from which, as a cluster of the mesoscopic range, one can expect unusual material properties. A central O33 polyhedron (shown on the right) defines the unusual cavity of this giant cluster and points to interesting host-guest chemistry. The cluster has been characterized by numerous analytical and spectroscopic methods.
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