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Reversible formation of high-valent-iron-oxo porphyrin intermediates in heme-based catalysis: revisiting the kinetic model for horseradish peroxidase

Heme-based CatalysisChemical EngineeringChemical KineticsHorseradish PeroxidaseEngineeringBiochemistryReversible FormationNatural SciencesHeme DegradationCatalysisRedox ChemistryChemistryRedox BiologyDeoxygenation