Publication | Closed Access
(<i>n</i>Bu<sub>4</sub>P)<sub>2</sub>[Os<sub>20</sub>(CO)<sub>40</sub>], a Thermolytically Generated High‐Nuclearity Cluster with a Tetrahedral Cubic‐Close‐Packed Metal Core
50
Citations
12
References
1991
Year
EngineeringNuclear PhysicsChemistryInorganic CompoundNuclear MaterialsOsos DistancesNuclear ReactorsMaterials ScienceInorganic ChemistryCluster SciencePhysicsElemental OsmiumNuclear ReactionsPhysical ChemistryQuantum ChemistryCrystallographyCrystal Structure DesignElectrochemistryNatural SciencesHigh‐nuclearity ClusterCluster ChemistrySymmetrical Osmium Tetrahedron
A fully symmetrical osmium tetrahedron consisting of twenty cubic-close-packed metal atoms constitutes the framework of dianion 1. There is no evidence for interstitial carbon or hydrogen atoms in the framework. Moreover, the OsOs distances approach those of elemental osmium. Cyclovoltammetric measurements indicate that 1 exhibits interesting electrochemical properties (see also the Highlight on p. 72).
| Year | Citations | |
|---|---|---|
Page 1
Page 1