The first ligand-modulated oxidative Heck vinylation. Efficient catalysis with molecular oxygen as palladium(0) oxidantElectronic Supplementary Information (ESI) available: Experimental and analytical data. See http://www.rsc.org/suppdata/cc/b3/b311492a/

Abstract

The discovery of the first ligand-supported Pd(II) catalysed oxidative Heck reaction with molecular oxygen as reoxidant and the scope with diverse arylboronic acids and olefins using only 1–2% of catalyst are reported.