A Novel Electrophilic Diamination Reaction of Alkenes

Abstract

A three-component electrophilic reaction transforms olefins into imidazoline and diamine derivatives (see scheme). Rhodium(II) heptafluorobutyrate dimer (2 mol %) was utilized as the catalyst and N,N-dichloro-p-toluenesulfonamide (TsNCl2) and acetonitrile as the nitrogen sources. Modest to good yields (45–82 %) and high regio- and stereoselectivity were achieved.