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Chiral‐Mn(Salen)‐Complex‐Catalyzed Kinetic Resolution of Secondary Alcohols in Water
128
Citations
38
References
2003
Year
Chemical EngineeringEngineeringKinetic ResolutionGreen ChemistryOrganic ChemistryOrganometallic CatalysisCatalysisHomogeneous CatalysisChemistryGreen MethodSecondary AlcoholsCatalytic ProcessAsymmetric CatalysisChemical KineticsMolecular CatalysisCatalytic SynthesisPtc=phase-transfer Catalyst
A mild, green method for enantioselective kinetic resolution of secondary alcohols has been developed using Mn(salen) complexes as catalysts in water. Up to 97.8 % ee was attained. PTC=phase-transfer catalyst. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z50464_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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