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Effect of Air Contaminants on the Electrolyte Degradation in Polymer Electrolyte Membrane Fuel Cells
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2009
Year
Environmental ElectrochemistryChemical EngineeringEngineeringF− Release RateAir ContaminantsElectrolyzer CellEnvironmental EngineeringElectrodialysisElectrolyte DegradationProton-exchange MembraneEnergy StoragePolymer MembranesChemistrySulfur-poisoned Pt CatalystPolymer MembraneElectrochemistry
The effect of air contaminants (NH3, NO2, H2S, and SO2) on electrolyte degradation was evaluated in PEMFCs. 2 ppm of these contaminants were supplied, and the F− release rate in the cathode effluent water was analyzed under a current density of 1000 mA/cm2 at 80 {degree sign}C. In the case of sulfur species H2S and SO2, a significant decrease in cell voltage and an increase in F− release rate were observed. The electrolyte degradation appears to be accelerated by hydroxyl radicals generated from H2O2, which was produced by a sulfur-poisoned Pt catalyst. 19F-NMR analysis of the sulfur-poisoned MEA revealed that the degradation of the cathode ionomer was significant compared to the anode ionomer and the membrane. Degradation of the cathode ionomer was confirmed by experiment with the MEA composed of a hydrocarbon-based membrane and a perfluorosulfonic acid ionomer, in which an increase in the F− release rate was also observed.