Concepedia

Gold-catalyzed cyclo-isomerization of 1,6-diyne-4-en-3-ols to form naphthyl ketone derivatives

Jian‐Jou Lian, Rai‐Shung Liu

Chemical Communications · 2007 · 67 citations · 43 references

DOI

Concepts

Abstract

We report a new efficient gold-catalyzed cyclization of 1,6-diyne-4-en-3-ols to give naphthyl ketone derivatives under ambient conditions. The value of this cyclization is reflected by its applicability to a wide range of alcohol substrates.

References

43

Gold and Platinum Catalysis of Enyne Cycloisomerization

Liming Zhang, Jianwei Sun, Sergey A. Kozmin · Advanced Synthesis & Catalysis · 2006 · 889 citations

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Phosphine Gold(I) Bis-(trifluoromethanesulfonyl)imidate Complexes as New Highly Efficient and Air-Stable Catalysts for the Cycloisomerization of Enynes

Nicolas Mézailles, Louis Ricard, Fabien Gagosz · Organic Letters · 2005 · 687 citations

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Cationic Gold(<scp>I</scp>) Complexes: Highly Alkynophilic Catalysts for the <i>exo</i>‐ and <i>endo</i>‐Cyclization of Enynes

Cristina Nieto‐Oberhuber, María Paz Muñoz, Elena Buñuel et al. · Angewandte Chemie International Edition · 2004 · 587 citations

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Tandem Au-Catalyzed 3,3-Rearrangement−[2 + 2] Cycloadditions of Propargylic Esters:  Expeditious Access to Highly Functionalized 2,3-Indoline-Fused Cyclobutanes

Liming Zhang · Journal of the American Chemical Society · 2005 · 454 citations

, , +13

AuCl<sub>3</sub>-Catalyzed Benzannulation:  Synthesis of Naphthyl Ketone Derivatives from <i>o</i>-Alkynylbenzaldehydes with Alkynes

Naoki Asao, Kumiko Takahashi, Sun Young Lee et al. · Journal of the American Chemical Society · 2002 · 424 citations

, , +14