Advanced Synthesis & Catalysis · 2011 · 156 citations · 27 references
Natural SciencesChemistryMedicinal ChemistryCatalysisOrganic ChemistrySynthetic Medicinal ChemistryCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MaterialsCatalytic MechanismsHeterocycle SynthesisCatalytic FunctionalizationFunctionalizationHeterocycle FunctionalizationIndole ChemistryIndole DerivativesIron CatalysisMild Reaction ConditionsTransition-metal-catalyzed Functionalization
Abstract An easily available iron catalyst was developed to accomplish the CH functionalization of indoles with α‐aryl‐α‐diazoesters in high yields under mild conditions. The asymmetric CH functionalization of indoles was also realized by using iron complexes of chiral spiro bisoxazolines with up to 78% ee .
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C-H Bond Functionalization in Complex Organic Synthesis
Kamil Godula, Dalibor Sameš · Science · 2006 · 2.1K citations