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The Structure of [Zn(bix)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>]·4.5 H<sub>2</sub>O (bix = 1,4‐Bis(imidazol‐1‐ylmethyl)benzene): A New Type of Two‐Dimensional Polyrotaxane
245
Citations
9
References
1997
Year
Materials ScienceInorganic ChemistryMetal Chain CompoundEngineeringLinear Chain CompoundNew TypePolyrotaxane ColumnsOrganic ChemistryInterpenetrating Polymer Network2-D RotaxaneCoordination PolymerChemistryTwo‐dimensional PolyrotaxaneUnprecedented TypeFunctional MaterialsPolymer ChemistryPolymers
Two independent and interpenetrating two-dimensional networks, whose outstanding structural features are the polyrotaxane columns of the unprecedented type shown on the right, are found in the coordination polymer [Zn(bix)2(NO3)2]·4.5 H2O. This compound is only the third example of a 2-D rotaxane; the other two were just recently reported.
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