Publication | Closed Access
On the relative migratory aptitudes of carbon and heteroatoms in borate complexes. A surprising α-thia effect
15
Citations
12
References
2004
Year
Inorganic ChemistryBiogeochemistryEngineeringHeterocyclicBiochemistry1,2-Alkyl MigrationNatural SciencesSurprising α-Thia EffectOrganic ChemistryOrganometallic CatalysisRelative Migratory AptitudesChemistry1,2-Sulfur MigrationBorate ComplexesHeterocycle ChemistryBiomolecular EngineeringDimethylsulfoxonium Methylide
Dimethylsulfoxonium methylide reacts with dicyclohexyl alpha-thiophenylmethyl)methylborane via 1,2-alkyl migration and alkyldithiaborolane via 1,2-sulfur migration.
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