[(enH<sub>2</sub>)<sub>0.5</sub>][Zr<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>(HPO<sub>4</sub>)F]·H<sub>2</sub>O: A Unique Zirconium Fluoride Phosphate with a Cavity Structure

Erhard Kemnitz, M. Wloka, S. Trojanov, A. Stiewe

Angewandte Chemie International Edition in English · 1996 · 45 citations · 14 references

Concepts

Abstract

Medium-sized channels pass through the structure of the first zinc fluoride phosphate (section of the structure is shown on the right). The framework is constructed from ZrO6 and ZrO5F octahedra and PO4 and PO3(OH) tetrahedra. Further cavity-containing compounds of this type should be accessible by variation of the amine used as a template.

References

14