Highly Efficient and Stable CeNiH<sub><i>Z</i></sub>O<sub><i>Y</i></sub> Nano‐Oxyhydride Catalyst for H<sub>2</sub> Production from Ethanol at Room Temperature

Cyril Pirez, Mickaël Capron, Hervé Jobic, Franck Dumeignil, Louise Jalowiecki‐Duhamel

Angewandte Chemie International Edition · 2011 · 49 citations · 29 references

Concepts

Abstract

The CeNiHZOY oxyhydride compound is an exceptional catalyst that totally converts ethanol at 60 °C and produces H2 in the presence of water and oxygen. The H2 fraction of the gas-phase products is about 50 % (see picture; c: conversion, p: production). The oxyhydride compound is formed by in-situ activation of CeNiOY with H2 at 250 °C. The presence of hydride species in the catalyst is evidenced by inelastic neutron scattering.

References

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