Angewandte Chemie International Edition · 2011 · 49 citations · 29 references
Natural SciencesChemical EngineeringChemistryCatalysisReaction EngineeringCatalyst DesignCatalyst PreparationCatalyst StabilityCatalyst SynthesisCatalytic MechanismsNanocatalysisCatalyst MechanismsNanocatalyst DesignNanocatalyst SynthesisNanostructured CatalystsOxidative Catalysis
The CeNiHZOY oxyhydride compound is an exceptional catalyst that totally converts ethanol at 60 °C and produces H2 in the presence of water and oxygen. The H2 fraction of the gas-phase products is about 50 % (see picture; c: conversion, p: production). The oxyhydride compound is formed by in-situ activation of CeNiOY with H2 at 250 °C. The presence of hydride species in the catalyst is evidenced by inelastic neutron scattering.
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