Concepedia

(CN3H6)4[Zn3(SeO3)5]: The First Organically Templated Selenite

William T. A. Harrison, Mark L. F. Phillips, Jesse Stanchfield, Tina M. Nenoff

Angewandte Chemie International Edition · 2000 · 98 citations · 11 references

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Abstract

A completely different structure to that of any “inorganic” selenite is exhibited by the organically templated title compound. One of the guanidinium cations displays a particularly clear template effect in occupying a 12-ring window and bonding to the inorganic network by way of N−H⋅⋅⋅O hydrogen bonds (see picture).

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