Angewandte Chemie International Edition · 2006 · 43 citations · 22 references
Natural SciencesChemistryChemical KineticsOrganic ChemistryOrganometallic ChemistryChemical BondingCoordination ChemistryLigand BindingMetal-ligand BondingReaction MechanismsTransition Metal ComplexesC-h Bond ActivationKinetic Studies Of Organometallic ReactionsKinetics Of Coordination CompoundsLigand Effects On ReactivityLigand Exchange Reactions
The first reversible and regiospecific H/D exchange promoted by CuI proceeds in weakly coordinating deuterated “acidic” solvents, such as [D6]acetone or [D4]methanol (see scheme). The kinetics of the reaction have been studied in both directions (H/D and D/H exchange) by 1H and 2H NMR spectroscopy, and a molecular mechanism is proposed that is in accordance with all experimental and theoretical data.
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Activation of a carbon–carbon bond in solution by transition-metal insertion
Michael Gozin, Alexander Weisman, Yehoshua Ben‐David et al. · Nature · 1993 · 301 citations
Confusion Approach to Porphyrinoid Chemistry
A. Srinivasan, Hiroyuki Furuta · Accounts of Chemical Research · 2004 · 276 citations