Asian Journal of Organic Chemistry · 2013 · 165 citations · 62 references
Natural SciencesChemistryMaterials ChemistryMolecular PhysicsPhysical ChemistryChemical BondingHeterocyclic ChemistryMolecular BondingRadical ReactionsReaction MechanismsDirect Reaction Mechanisms
Abstract Recent studies of aryne chemistry have left some unexplained details in their reactivity, reaction mechanisms, and structure‐activity relationships. This Focus Review summarizes some of the questions and findings that we do not expect or understand. Further studies of these details will hopefully enrich aryne chemistry to provide further understanding and find more applications of aryne chemistry.
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The hexadehydro-Diels–Alder reaction
Thomas R. Hoye, Beeraiah Baire, Dawen Niu et al. · Nature · 2012 · 427 citations · Full text