Synthesis and Characterization of a Stable, Catenated N₁₁ Energetic Salt

Abstract

A nitrogen-rich energetic salt containing the longest reported nitrogen chain (N11), was obtained by an azo coupling reaction from 1,5-diaminotetrazole. This is the first example of an azo reaction between an NNH2 diazonium salt and an amine derivative. The product structure was confirmed by X-ray crystallography, and its physical and explosive properties were characterized. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.