Lattice Expansion of Highly Oriented 2D Phthalocyanine Covalent Organic Framework Films

Eric L. Spitler, John Colson, Fernando J. Uribe‐Romo, Arthur R. Woll, Marissa Giovino, Abraham Saldivar, William R. Dichtel

Angewandte Chemie International Edition · 2012 · 286 citations · 37 references

Concepts

Abstract

Expanding into application: Covalent organic framework (COF) films are ideally suited for vertical charge transport and serve as precursors of ordered heterojunctions. Their pores, however, were previously too small to accommodate continuous networks of complementary electron acceptors. Four phthalocyanine COFs with increased pore size well into the mesoporous regime are now described (see picture). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

37