Angewandte Chemie International Edition · 2009 · 180 citations · 54 references
Natural SciencesChemistryCatalysisOrganic ChemistryOrganic Synthesis
One for the Rh(oad): The first rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated olefins was developed by using dialkylbiaryl phosphine ligands (see scheme; cod=1,5-cyclooctadiene, Cy=cyclohexyl). A variety of 2-methylpyrrolidines have been synthesized with high enantioselectivities.
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Organolanthanide-Catalyzed Hydroamination
Sukwon Hong, Tobin J. Marks · Accounts of Chemical Research · 2004 · 1K citations
A Powerful Chiral Counterion Strategy for Asymmetric Transition Metal Catalysis
Gregory L. Hamilton, Eun Joo Kang, Miriam Mba et al. · Science · 2007 · 902 citations
David W. Old, John P. Wolfe, Stephen L. Buchwald · Journal of the American Chemical Society · 1998 · 811 citations