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Nickel(II) Phosphate VSB-5: A Magnetic Nanoporous Hydrogenation Catalyst with 24-Ring Tunnels

DOI

324

Citations

14

References

2001

Year

Nathalie Guillou, Qiuming Gao, Paul M. Forster, Jong‐San Chang, Marc Noguès, Sang‐Eon Park, Gérard Férey, Anthony K. Cheetham
Angewandte Chemie International Edition

Abstract

Nanoporosity, good thermal stability, antiferromagnetic ordering, and hydrogenation with basic catalytic character are four important properties of the large-pore (24MR), zeolitic nickel(II) phosphate, VSB-5 (Ni<sub>20</sub> [(OH)<sub>12</sub> (H<sub>2</sub> O)<sub>6</sub> ][(HPO<sub>4</sub> )<sub>8</sub> (PO<sub>4</sub> )<sub>4</sub> ]⋅12 H<sub>2</sub> O), which has been prepared under alkaline hydrothermal conditions. The structure of VSB-5 is depicted: NiO<sub>6</sub> octahedra: green; PO<sub>4</sub> tetrahedra: red.

References

YearCitations

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