Efficient CuO‐Nanoparticle‐Catalyzed CS Cross‐Coupling of Thiols with Iodobenzene

Laxmidhar Rout, Tamal K. Sen, Tharmalingam Punniyamurthy

Angewandte Chemie International Edition · 2007 · 339 citations · 52 references

Concepts

Abstract

Cheap but good: Readily available CuO nanoparticles are not only less expensive than other catalysts used for the CS cross-coupling of thiols with aryl halides, but they are also effective at a moderate temperature and low concentration. The title reaction proceeds with a variety of alkyl and aryl thiols to give the corresponding sulfides in high yields (see scheme).

References

52