Angewandte Chemie International Edition · 2007 · 339 citations · 52 references
Natural SciencesChemistryMaterials ScienceCatalysisInorganic ChemistryNanomaterialsCatalyst DesignCross-coupling ReactionsInorganic NanoparticlesMetal Oxide NanomaterialsMetal SulfidesNanocatalysisCopper Oxide NanostructuresCopper-catalyzed CouplingMetal Sulfide NanomaterialsMetal Sulfide NanostructuresNanoparticle CatalysisSurface Chemistry Of Metal SulfidesThiol ChemistryThiol Functionalization
Cheap but good: Readily available CuO nanoparticles are not only less expensive than other catalysts used for the CS cross-coupling of thiols with aryl halides, but they are also effective at a moderate temperature and low concentration. The title reaction proceeds with a variety of alkyl and aryl thiols to give the corresponding sulfides in high yields (see scheme).
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James T. Lindley · Tetrahedron · 1984 · 2.2K citations
Copper in cross-coupling reactions
I. P. Beletskaya, Andrei V. Cheprakov · Coordination Chemistry Reviews · 2004 · 1.5K citations