Chemical Communications · 2010 · 644 citations · 180 references
Natural SciencesChemistryMaterials ScienceOptical MaterialsOptoelectronicsPhotonicsLight HarvestingOrganic SemiconductorsPhotochemistryPhotovoltaic DevicesPhotovoltaic MaterialsSolar CellsElectron TransferExtinctionExtinction CoefficientsOrganic Photovoltaic CellsOrganic PhotovoltaicsOrganic Solar CellsPhotochemical Energy ConversionPhysical Properties
The field of organic photovoltaics (OPV) represents one of the most promising technological areas. Porphyrins and phthalocyanines are perfectly suited for their integration in light energy conversion systems. These colored macrocycles exhibit very attractive physical properties, particularly very high extinction coefficients in the visible and near IR regions, where the maximum of the solar photon flux occurs, that is necessary for efficient photon harvesting, besides a rich redox chemistry, as well as photoinduced electron transfer and semiconducting capabilities.
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Two-layer organic photovoltaic cell
C. W. Tang · Applied Physics Letters · 1986 · 4.9K citations
Natural Sciences, Materials Engineering, Materials Science +17
Michaël Grätzel · Journal of Photochemistry and Photobiology C Photochemistry Reviews · 2003 · 4.3K citations · Full text