Concepedia

Cyclopropanation of alkenes with ethyl diazoacetate catalysed by ruthenium porphyrin complexes

Erwan Galardon, Paul Le Maux, Gérard Simonneaux

Chemical Communications · 1997 · 96 citations · 10 references

DOI

Concepts

Abstract

Ruthenium porphyrin complexes are active catalysts for the cyclopropanation of styrene derivatives by ethyl diazoacetate with good to very good diastereoselectivity; moderate enantiomeric excesses (34%) are observed using a chiral porphyrin as catalyst.

References

10

New Chiral Ruthenium Bis(oxazolinyl)pyridine Catalyst. Efficient Asymmetric Cyclopropanation of Olefins with Diazoacetates

Hisao Nishiyama, Yoshiki Itoh, Hideki Matsumoto et al. · Journal of the American Chemical Society · 1994 · 407 citations

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Shape and stereoselective cyclopropanation of alkenes catalyzed by iron porphyrins.

Jennifer R. Wolf, Christopher G. Hamaker, Jean‐Pierre Djukic et al. · Journal of the American Chemical Society · 1995 · 247 citations

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A highly enantioselective synthesis of cyclopropane derivatives through chiral cobalt(II) complex catalyzed carbenoid reaction. General scope and factors determining the enantioselectivity

Akira Nakamura, Akira Konishi, Yoshitaka Tatsuno et al. · Journal of the American Chemical Society · 1978 · 190 citations

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The Cyclopropyl Group in Studies of Enzyme Mechanism and Inhibition

Colin J. Suckling · Angewandte Chemie International Edition in English · 1988 · 177 citations

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Models of oxidized heme proteins. Preparation and characterization of a trans-dioxoruthenium(VI) porphyrin complex

John T. Groves, Robert E. Quinn · Inorganic Chemistry · 1984 · 164 citations

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