Dynamical Ising-like model for the two-step spin-crossover systems

Abstract

In order to reproduce the two-step relaxation observed experimentally in spin-crossover systems, we investigate analytically the static and the dynamic properties of a two-sublattice Ising-like Hamiltonian. The formalism is based on a stochastic master equation approach. It is solved in the mean-field approximation, and yields two coupled differential equations that correspond to the HS fractions of the sublattices A and B.