Platinum‐Promoted Ga/Al<sub>2</sub>O<sub>3</sub> as Highly Active, Selective, and Stable Catalyst for the Dehydrogenation of Propane

Jesper J. H. B. Sättler, Ines D. Gonzalez‐Jimenez, Lin Luo, Brien A. Stears, Andrzej Malek, David G. Barton, Beata A. Kilos, Mark Kaminsky, Tiny W.G.M Verhoeven, Eline J. Koers,

Angewandte Chemie International Edition · 2014 · 273 citations · 34 references

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Abstract

A novel catalyst material for the selective dehydrogenation of propane is presented. The catalyst consists of 1000 ppm Pt, 3 wt% Ga, and 0.25 wt% K supported on alumina. We observed a synergy between Ga and Pt, resulting in a highly active and stable catalyst. Additionally, we propose a bifunctional active phase, in which coordinately unsaturated Ga(3+) species are the active species and where Pt functions as a promoter.

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