Ligand Extrusion from the As<sub>4</sub>S<sub>4</sub>‐Cage by [C<sub>5</sub>Me<sub>5</sub>(CO)<sub>2</sub>Mo]<sub>2</sub>: Formation of (C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>Mo<sub>2</sub>(CO)<sub>4</sub>(μ,η<sup>2</sup>‐As<sub>2</sub>), C<sub>5</sub>Me<sub>5</sub>(CO)<sub>2</sub>Mo(η<sup>3</sup>‐As<sub>3</sub>), and (C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>Mo<sub>2</sub>As<sub>2</sub>S<sub>3</sub> - Concepedia

Concepedia

Publication | Closed Access

Ligand Extrusion from the As<sub>4</sub>S<sub>4</sub>‐Cage by [C<sub>5</sub>Me<sub>5</sub>(CO)<sub>2</sub>Mo]<sub>2</sub>: Formation of (C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>Mo<sub>2</sub>(CO)<sub>4</sub>(μ,η<sup>2</sup>‐As<sub>2</sub>), C<sub>5</sub>Me<sub>5</sub>(CO)<sub>2</sub>Mo(η<sup>3</sup>‐As<sub>3</sub>), and (C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>Mo<sub>2</sub>As<sub>2</sub>S<sub>3</sub>

68

Citations

6

References

1984

Year

Ivan Bernal, Henri Brunner, Walter Meier, Heike Pfisterer, Joachim Wächter, Manfred L. Ziegler

Angewandte Chemie International Edition in English

Unusual Complexes—interInorganic ChemistryEngineeringBiochemistryAss LigandNatural SciencesLigand ExtrusionCoordination ComplexUnknown Title ReactionMolecular ComplexChemistryCrystallographyInorganic SynthesisBiomolecular EngineeringInorganic Compound

Abstract

Three unusual complexes—inter alia the first complex with an AsS ligand and a monosubstituted derivative of yellow arsenic—were obtained via the previously unknown title reaction of realgar.

References

	Year	Citations

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