Angewandte Chemie International Edition · 2006 · 313 citations · 53 references
Natural SciencesChemical EngineeringChemistryCatalysisNanomaterialsReaction EngineeringCatalyst StabilityCatalytic MaterialsCatalytic MechanismsCatalytic Reaction EngineeringNanocatalysisSupported CatalystsAlcohol OxidationCatalyst MechanismsCatalyst RecyclingCatalyst Structure-activity RelationshipsMesoporous MaterialsNanoparticlesNanostructured CatalystsPalladium Catalysts
Scaling down the activity: An efficient recyclable palladium-based catalyst has been developed for the aerobic oxidation of alcohols (see scheme). The combination of a substituted bipyridyl ligand and ordered mesoporous channels (in SBA) causes a synergistic effect that results in enhanced activity, the prevention of agglomeration of the palladium nanoparticles, and the generation of a durable catalyst.
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