Publication | Closed Access
Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent <i>N</i>‐Oxyl Radical
191
Citations
43
References
2011
Year
Radical EmissionEngineeringBiochemistryNew TypeNatural SciencesReactive Nitrogen SpecieRadical (Chemistry)Frustrated Lewis PairOrganic ChemistryOrganometallic CatalysisCatalysisLewis PairChemistryMolecular ChemistryReaction IntermediateRedox ChemistryH-atom Abstraction ReactivityO-functionalized P/b-flp-nor Species
NO your pairs: The intramolecular frustrated Lewis pair (FLP) Mes2PCH2CH2B(C6F5)2 captures NO to give the novel N-oxyl radical P/B-FLP-NO. (see scheme). Coordination of NO to the FLP incites H-atom abstraction reactivity with cyclohexene and ethylbenzene to give P/B-FLP-NOH and the O-functionalized P/B-FLP-NOR species.
| Year | Citations | |
|---|---|---|
Page 1
Page 1