The Largest Synthetic Structure with Molecular Precision: Towards a Molecular Object

Baozhong Zhang, Roger Wepf, Karl Fischer, Manfred Schmidt, Sébastien Besse, Peter Lindner, Benjamin T. King, R. Sigel, Peter Schurtenberger, Yeshayahu Talmon,

Angewandte Chemie International Edition · 2010 · 119 citations · 31 references

Concepts

Abstract

Pushing the limits: A 200×106 Da structurally defined, linear macromolecule (PG5) has a molar mass, cross-section dimension, and cylindrical shape that are comparable to some naturally occurring objects, such as amyloid fibrils or certain plant viruses. The macromolecule is resistant against flattening out on a surface; the picture shows PG5 embracing the tobacco mosaic virus (TMV). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

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